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Fate of phosphorus in fluidized bed cocombustion of chicken litter with wheat straw and bark residues
Energy Engineering, Division of Energy Science, Luleå University of Technology, Luleå, Sweden.
Bioenergy2020+ GmbH, Güssing, Austria; Institute of Chemical, Environmental & Bioscience Engineering, TU Wien, Vienna, Austria.
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics. Energy Engineering, Division of Energy Science, Luleå University of Technology, Luleå, Sweden; Bioenergy2020+ GmbH, Güssing, Austria; Institute of Chemical, Environmental & Bioscience Engineering, TU Wien, Vienna, Austria.ORCID iD: 0000-0003-3863-5186
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics. (Thermochemical Energy Conversion Laboratory)ORCID iD: 0000-0002-5777-9241
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2020 (English)In: Energy & Fuels, ISSN 0887-0624, E-ISSN 1520-5029, Vol. 34, no 2, p. 1822-1829Article in journal (Refereed) Published
Abstract [en]

This study aims to determine the fate of P during fluidized bed co-combustion of chicken litter (CL) with K-rich fuels [e.g., wheat straw (WS)] and Ca-rich fuels (bark). The effect of fuel blending on phosphate speciation in ash was investigated. This was performed by chemical characterization of ash fractions to determine which phosphate compounds had formed and identify plausible ash transformation reactions for P. The ash fractions were produced in combustion experiments using CL and fuel blends with 30% CL and WS or bark (B) at 790–810 °C in a 5 kW laboratory-scale bubbling fluidized bed. Potassium feldspar was used as the bed material. Bed ash particles, cyclone ash, and particulate matter (PM) were collected and subjected to chemical analysis with scanning electron microscopy–energy-dispersive X-ray spectrometry (SEM–EDS) and X-ray diffraction. P was detected in coarse ash fractions only, that is, bed ash, cyclone ash, and coarse PM fraction (>1 μm); no P could be detected in the fine PM fraction (<1 μm). SEM–EDS analysis showed that P was mainly present in K–Ca–P-rich areas for pure CL as well as in the ashes from the fuel blends of CL with WS or B. In the WS blend, P was found together with Si in these areas. The crystalline compound containing P was hydroxyapatite in all cases as well as whitlockite in the cases of pure CL and WS blend, of which the latter compound has been previously identified as a promising plant nutrient. The ash fractions from CL and bark blend only contained P in hydroxyapatite. Co-combustion of CL together with WS appears to be promising for P recovery, and ashes with this composition could be further studied in plant growth experiments.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2020. Vol. 34, no 2, p. 1822-1829
Keywords [en]
Phosphates, Chemical reactions, Fuels, Reaction products, Materials
National Category
Energy Engineering Other Chemistry Topics
Identifiers
URN: urn:nbn:se:umu:diva-157283DOI: 10.1021/acs.energyfuels.9b03652ISI: 000518215400072Scopus ID: 2-s2.0-85080856092OAI: oai:DiVA.org:umu-157283DiVA, id: diva2:1296101
Conference
27th International Conference of Impacts of Fuel Quality on Power Production and the Environment, 23–28 September, 2018, Lake Louise, Canada
Projects
Bio4Energy
Funder
Swedish Research Council Formas, 2015-619Bio4EnergyAvailable from: 2019-03-13 Created: 2019-03-13 Last updated: 2023-12-06Bibliographically approved

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Fürsatz, KatharinaKuba, MatthiasSkoglund, Nils

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