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Competing commercial catalysts: Unprecedented catalyst activity and stability of Mizoroki-Heck reaction in a continuous packed bed reactor
Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Turku/Åbo, Finland.
Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Turku/Åbo, Finland.
Umeå University, Faculty of Science and Technology, Department of Chemistry.ORCID iD: 0000-0002-4766-2672
Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Turku/Åbo, Finland.
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2022 (English)In: Chemical Engineering Journal, ISSN 1385-8947, E-ISSN 1873-3212, Vol. 433, article id 134432Article in journal (Refereed) Published
Abstract [en]

Main obstacle for adopting continuous processes as a standard technology for Mizoroki-Heck reaction usually lies in its specific reaction mechanism. Here we present an important step forward answering the challenges unraveled through a comprehensive study that provides deeper understanding on the Mizoroki-Heck reaction, in particular the case when iodobenzene and butyl acrylate react in a continuous packed bed reactor in the presence of a Pd Supported Ionic Liquid Catalyst (SILCA). On-line UV–VIS spectrometry supported by ICP-OES, TEM and XPS measurements were carried out and the catalyst leaching was minimized. Finally, simple continuous flow process was proposed resulting in a high catalytic activity (up to 1470 molArI molPd−1h−1) and reaching productivity in the range of 12,000 to 16,000 molArI molPd−1 thus competing with the performance of commercial catalysts.

Place, publisher, year, edition, pages
Elsevier, 2022. Vol. 433, article id 134432
Keywords [en]
Continuous flow, Heterogeneous catalysis, Mizoroki-Heck reaction, Release-and-catch mechanism, Supported ionic liquid catalyst
National Category
Chemical Process Engineering
Identifiers
URN: urn:nbn:se:umu:diva-191456DOI: 10.1016/j.cej.2021.134432ISI: 000773543000002Scopus ID: 2-s2.0-85122491311OAI: oai:DiVA.org:umu-191456DiVA, id: diva2:1629696
Funder
Bio4EnergySwedish Research Council
Note

Volume 433, Part 1.

Available from: 2022-01-18 Created: 2022-01-18 Last updated: 2023-09-05Bibliographically approved

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Shchukarev, AndreyMikkola, Jyri-Pekka

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