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Synthesis of three-dimensional ring fused heterocycles by a selective [4 + 2] cycloaddition between bicyclic thiazolo 2-pyridones and arynes
Umeå University, Faculty of Science and Technology, Department of Chemistry.ORCID iD: 0000-0003-1803-2708
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Centre for Analysis and Synthesis, Lund University, Lund, Sweden.
Centre for Analysis and Synthesis, Lund University, Lund, Sweden.
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2024 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 89, no 1, p. 731-739Article in journal (Refereed) Published
Abstract [en]

A selective [4 + 2] cycloaddition reaction of thiazolo-2-pyridones with arynes has been demonstrated. The developed protocol allows rapid access to highly functionalized, structurally complex thiazolo-fused bridged isoquinolones in high yields, which are susceptible to further late-stage functionalization.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2024. Vol. 89, no 1, p. 731-739
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-219753DOI: 10.1021/acs.joc.3c01957ISI: 001137559200001PubMedID: 38093677Scopus ID: 2-s2.0-85180992605OAI: oai:DiVA.org:umu-219753DiVA, id: diva2:1830165
Funder
NIH (National Institutes of Health), R01AI134847-01A1NIH (National Institutes of Health), 1U19AI157797-01Familjen Erling-Perssons Stiftelse, P20-00473Swedish Research Council, 2018-04589Swedish Research Council, 2021-05040JThe Kempe Foundations, SMK-1755Available from: 2024-01-22 Created: 2024-01-22 Last updated: 2024-01-22Bibliographically approved

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Sarkar, SouvikSingh, PardeepAlmqvist, Fredrik

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