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Achieving optically selective coatings of silica fixated carbon nanotubes for solar energy applications
Umeå University, Faculty of Science and Technology, Department of Physics. Absolicon Solar Collector AB, Härnösand, Sweden.
Umeå University, Faculty of Science and Technology, Department of Physics.ORCID iD: 0009-0002-9248-5748
Umeå University, Faculty of Science and Technology, Department of Physics. Absolicon Solar Collector AB, Härnösand, Sweden.
Umeå University, Faculty of Science and Technology, Department of Physics.
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2024 (English)In: Solar Energy Materials and Solar Cells, ISSN 0927-0248, E-ISSN 1879-3398, Vol. 278, article id 113202Article in journal (Refereed) Published
Abstract [en]

Solar collectors have the potential for significant climate change mitigation by substituting heat produced with fossil fuels. To achieve this, collectors with highly efficient solar absorbers are essential. Carbon nanotubes are highly absorbing, sustainable, cheap, and thermally stable, making them a promising material for solar absorbers. However, achieving a high solar absorptance and low thermal emittance (solar selectivity), while maintaining good thermal stability and scalability is challenging. Here, we present a selective coating based on multi-walled carbon nanotubes and silica (SiO2). A water-based dispersion enabled by carboxyl functionalization of the carbon nanotubes (CNTF) is spray coated on a stainless steel (SS) substrate and fixated with sol-gel dip coated silica. The SS/CNTF/SiO2 surface exhibits an optical selectivity dependent on CNTF area load and with 0.83 gCNT m−2 a solar absorptance and thermal emittance of 0.94 and 0.40, respectively, is achieved. The coating also demonstrates excellent thermal stability, with an estimated lifetime of >25 years at working temperatures ≤222°C. All together, we show that by using scalable and cheap technology, concurrent with sustainable materials and a simple structural design, we can manufacture a coating that exhibits properties suitable for low-to-mid-temperature applications. Our study highlights the potential of carbon-based solar absorbers.

Place, publisher, year, edition, pages
Elsevier, 2024. Vol. 278, article id 113202
Keywords [en]
Carbon nanotubes, Solar absorber, Solar energy, Solar selective coating, Solar thermal, Spray coating
National Category
Energy Engineering Physical Sciences
Identifiers
URN: urn:nbn:se:umu:diva-230981DOI: 10.1016/j.solmat.2024.113202Scopus ID: 2-s2.0-85205931081OAI: oai:DiVA.org:umu-230981DiVA, id: diva2:1908602
Funder
Knut and Alice Wallenberg FoundationAvailable from: 2024-10-28 Created: 2024-10-28 Last updated: 2025-02-04Bibliographically approved

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Zäll, ErikSegervald, JonasMahmoodi, HodaPerivoliotis, DimitriosEdman, LudvigWågberg, Thomas

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