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Precision frequency comb spectroscopy of the 14N2O, 14N15NO, 15N14NO, and 15N2O isotopocules in the 3300 – 3550 cm–1 range
Umeå University, Faculty of Science and Technology, Department of Physics.ORCID iD: 0000-0001-6144-4957
Umeå University, Faculty of Science and Technology, Department of Physics. Leibniz Institute for Plasma Science and Technology (INP), Greifswald, Germany; Experimental Physics V, Faculty of Physics and Astronomy, Ruhr University Bochum, Bochum, Germany.ORCID iD: 0000-0001-8082-5229
Umeå University, Faculty of Science and Technology, Department of Physics.ORCID iD: 0000-0002-6191-7926
2025 (English)In: Journal of Quantitative Spectroscopy and Radiative Transfer, ISSN 0022-4073, E-ISSN 1879-1352, Vol. 340, article id 109452Article in journal (Refereed) Published
Abstract [en]

Nitrous oxide is a long-lived greenhouse gas. Its isotopic composition provides valuable insights into sources and sinks, and about the mechanisms of formation. A major challenge in the spectroscopic analysis of the isotopocule compositions is the availability of accurate spectroscopic parameters, particularly for the minor 15N isotopocules. In this work, we introduce high-resolution spectroscopic measurements of four isotopocules of nitrous oxide: 14N2O, 14N15NO, 15N14NO, and 15N2O in the mid-infrared range of 3300 – 3550 cm–1 using a frequency comb-based Fourier transform spectrometer. The nitrous oxide samples were obtained from a chemical synthesis involving acid-catalyzed amine-borane reduction of equimolar amounts of 15N isotopically enriched sodium nitrite and 14N sodium nitrite. The high-resolution spectra, measured in a temperature-controlled single-pass absorption cell, were used to retrieve line center frequencies and relative intensities for a total of 426 rovibrational transitions of the ν1 + ν3 band of the four isotopocules, and of the one order of magnitude weaker 2ν2 + ν3 and ν1 + ν2 + ν3 – ν2 bands in the same spectral region. We compare the determined line center frequencies and relative intensities with spectroscopic parameters available in high-resolution molecular databases. For 14N2O, 14N15NO and 15N14NO we find good agreement with the HITRAN database. The 15N2O isotopocule is missing in HITRAN, and we find that its line center frequencies in the GEISA database, the Institute of Atmospheric Optics database, as well as the Ames-1 line list deviate severely from the comb measurements.

Place, publisher, year, edition, pages
Elsevier, 2025. Vol. 340, article id 109452
Keywords [en]
Fourier transform spectroscopy, Frequency comb spectroscopy, High-resolution spectroscopy, Line lists, Minor isotopocules, Nitrous oxide
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:umu:diva-238443DOI: 10.1016/j.jqsrt.2025.109452ISI: 001464472400001Scopus ID: 2-s2.0-105001803425OAI: oai:DiVA.org:umu-238443DiVA, id: diva2:1957466
Funder
Swedish Research Council, 2020-00238Knut and Alice Wallenberg Foundation, 2020.0303Available from: 2025-05-09 Created: 2025-05-09 Last updated: 2025-05-09Bibliographically approved

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Hjältén, AdrianSadiek, IbrahimFoltynowicz, Aleksandra

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