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Coffee pulp and husk-derived hydrochars and biochars adsorb polyphenols and pesticides from wastewater
Umeå University, Faculty of Science and Technology, Department of Chemistry. Department of Chemistry, College of Science and Technology, University of Rwanda, PO Box 3900, Kigali, Rwanda.
Department of Energy and Technology, Swedish Agricultural University, Uppsala, Sweden.
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics.ORCID iD: 0000-0003-4428-3201
School of Engineering, College of Science and Technology, University of Rwanda, PO Box 3900, Kigali, Rwanda.
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2026 (English)In: Environmental Technology & Innovation, ISSN 2352-1864, Vol. 41, article id 104739Article in journal (Refereed) Published
Abstract [en]

Coffee processing generates significant amounts of wastewater rich in organic compounds and sometimes also pesticides. This poses environmental challenges for producing regions. This study aimed to assist coffee producers by providing local waste management solutions by examining the adsorption efficiency of hydrochars and biochars derived from coffee pulps (CP) and coffee husks (CH) in removing polyphenols and pesticides from coffee processing wastewater (CPWW). These materials were tested for the adsorption of selected polyphenols and pesticides from CPWW. Hydrochars exhibited high removal efficiencies for polyphenols (up to 100 %), primarily via hydrogen bonding, while biochars effectively adsorbed hydrophobic pesticides (removal efficiencies up to ∼75 %) through hydrophobic interactions. Adsorption data fitted the Freundlich isotherm, indicating multilayer adsorption, and kinetic analyses suggested complex mechanisms involving both physisorption and chemisorption. These findings demonstrate the potential of coffee waste-derived chars to serve as sustainable adsorbents for mitigating pollution from CPWW, offering a promising local waste management strategy in coffee-producing countries.

Place, publisher, year, edition, pages
Elsevier, 2026. Vol. 41, article id 104739
Keywords [en]
Coffee Byproduct Valorization, Coffee Processing Wastewater Treatment, Hydrochar and Biochar Adsorption, Pesticide Adsorption, Polyphenol Removal
National Category
Environmental Sciences Environmental Sciences and Nature Conservation
Identifiers
URN: urn:nbn:se:umu:diva-249147DOI: 10.1016/j.eti.2025.104739Scopus ID: 2-s2.0-105027988814OAI: oai:DiVA.org:umu-249147DiVA, id: diva2:2035079
Funder
Sida - Swedish International Development Cooperation AgencyAvailable from: 2026-02-03 Created: 2026-02-03 Last updated: 2026-02-03Bibliographically approved

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Mukarunyana, BrigitteBoman, ChristofferFick, Jerker

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