Umeå University's logo

umu.sePublications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Numerical modelling of calcination of limestone: An evaluation of existing calcination model
Umeå University, Faculty of Science and Technology, Department of Applied Physics and Electronics.
2021 (English)Independent thesis Advanced level (professional degree), 20 credits / 30 HE creditsStudent thesis
Abstract [en]

Calcination is important for modern society as we know it since products from the reaction is used inseveral industries. Calcination is a chemical reaction where a solid particle, e.g., limestone, is exposedto high temperature which causes volatile impurities to be released from the particle.One of the main challenges with lime production is the mere scale of commercial production. Ensuringgood calcination and high-quality lime in laboratory scale is relatively easy, whereas commercial limekilns produce 100 – 800 tons lime each day, causing the conditions to be much more challenging. Theenvironment inside a lime kiln is extreme, with temperatures exceeding 1200°C, and a moving stonebed makes measurements difficult to perform. To obtain information about the calcination processand the extreme environment that arises in commercial lime kilns, companies and researchers havedeveloped simulation programmes to evaluate how changes in ambient condition affect the calcinationprocess.In this project, a shrinking core model has been used to simulate calcination of limestone with variedgeometry and size in different ambient condition. A transient model was used to simulate the heatingphases before and after the calcination phase. The results obtain from the simulation are compared tomeasured data obtain by others.There are many similarities between the measured data and the simulation, a reoccurringphenomenon is that the transit model, during the pre-heating, heats the limestone faster compared tothe measured data. However, in one case, the transient model is slower. A reason for this may be thatthe transient model does not account for morphological effects, as they are included in the heattransfer coefficient instead, such as the thermal conductivity coefficient and specific heat transfercoefficient. The post heating phase, after the reaction phase, required further work.The simulation with the Shrinking core model shows that a cylindrical geometry requires longercalcination duration, or a higher ambient temperature compared to a spherical geometry, even if bothgeometries have same material properties and radius. The factor with the most influence uponcalcination time is the ambient temperature in combination with reaction temperature. A highercarbon dioxide pressure, above atmospheric CO2 partial pressure, has relatively small effect comparedto a low ambient temperature, less than 1000°C.

Place, publisher, year, edition, pages
2021. , p. 34
Keywords [en]
Simulation, Modelling, Numerical, Shrinking core model, Calcination, Limestone
National Category
Chemical Engineering Energy Engineering
Identifiers
URN: urn:nbn:se:umu:diva-184517OAI: oai:DiVA.org:umu-184517DiVA, id: diva2:1566170
External cooperation
Centre for Sustainable Cement and Quicklime Production
Subject / course
Energiteknik
Educational program
Master of Science Programme in Energy Engineering
Supervisors
Examiners
Available from: 2021-06-15 Created: 2021-06-14 Last updated: 2025-02-18Bibliographically approved

Open Access in DiVA

fulltext(1601 kB)6794 downloads
File information
File name FULLTEXT01.pdfFile size 1601 kBChecksum SHA-512
da0ac914177a9e22dcc47c8558d5442bed000fd6b244e372fd9e0f2d8d37b7ae953b4e8c09cc082c0d63949cb222680a9104f6be1043009d0ed4997715aa802c
Type fulltextMimetype application/pdf

By organisation
Department of Applied Physics and Electronics
Chemical EngineeringEnergy Engineering

Search outside of DiVA

GoogleGoogle Scholar
Total: 6826 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

urn-nbn

Altmetric score

urn-nbn
Total: 1591 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf