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Durability of antireflective SiO2 coatings with closed pore structure
Umeå University, Faculty of Science and Technology, Department of Physics. Absolicon Solar Collector AB, Härnösand, Sweden.
RISE Research Institutes of Sweden, Division of Built Environment, Department of Building and Real Estate, Glass unit, Växjö, Sweden.
RISE Research Institutes of Sweden, Division of Bioeconomy and Health, Department of Materials and Surface Design, Stockholm, Sweden.
Umeå University, Faculty of Science and Technology, Department of Physics.ORCID iD: 0009-0002-9248-5748
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2023 (English)In: Solar Energy Materials and Solar Cells, ISSN 0927-0248, E-ISSN 1879-3398, Vol. 261, article id 112521Article in journal (Refereed) Published
Abstract [en]

The use of antireflective coatings to increase the transmittance of the cover glass is a central aspect of achieving high efficiencies for solar collectors and photovoltaics alike. Considering an expected lifetime of 20–30 years for solar energy installations, the durability of the antireflective surfaces is essential. Here, a novel antireflective SiO2 coating with a hexagonally ordered closed pore structure, produced with an aerosol-based sol-gel method is benchmarked against two commercial coatings; produced with acid etching and sol-gel roll coating. The optical and mechanical properties together with contact angle characteristics were evaluated before and after various durability tests, including climate chamber tests, outdoor exposure, and abrasion. Compared to the commercial antireflective coatings with open pore structures, the novel coating performed in parity, or better, in all tests. Based on the results of humidity freeze and industrial climate chamber tests, it appears that the coating with closed pore structure has a better ability to prevent water adsorption. Additionally, the closed pore structure of the coating seems to minimize the accumulation of dirt and deposits. The abrasion and cleanability test further confirm the advantages of a closed pore structure, showcasing the coating's mechanical durability. While the coatings exhibit similar hardness and reduced elastic modulus, the closed pore coating proves to be even harder after undergoing the industrial climate chamber test, but also slightly more brittle, as indicated by the probability of crack initiation. In summary the closed pore structure is well suited for tempered and arid climates, making it a truly competitive alternative to existing antireflective coatings.

Place, publisher, year, edition, pages
Elsevier, 2023. Vol. 261, article id 112521
Keywords [en]
Accelerated ageing, Aerosol-based deposition, Antireflective coating, Durability, Solar collector, Solar glass
National Category
Manufacturing, Surface and Joining Technology Other Physics Topics
Identifiers
URN: urn:nbn:se:umu:diva-213706DOI: 10.1016/j.solmat.2023.112521ISI: 001066466100001Scopus ID: 2-s2.0-85168412921OAI: oai:DiVA.org:umu-213706DiVA, id: diva2:1792360
Funder
Vinnova, 2018-02588Swedish Research Council, 2017-59504862Swedish Research Council, 2021–04629Swedish Energy Agency, 45419-1Swedish Energy Agency, 52487- 1Available from: 2023-08-29 Created: 2023-08-29 Last updated: 2025-04-25Bibliographically approved
In thesis
1. Heating a sustainable future: optical coatings for solar collectors
Open this publication in new window or tab >>Heating a sustainable future: optical coatings for solar collectors
2025 (English)Doctoral thesis, comprehensive summary (Other academic)
Alternative title[sv]
Uppvärmning av en hållbar framtid : optiska beläggningar för solfångare
Abstract [en]

The green transition is the great undertaking of our time, and it will require significant ingenuity and change in all areas of society. Most urgently, perhaps, regarding energy, where the demand for transport, electricity and heat must be met by renewables instead of fossil fuels. Solar thermal is one alternative with the potential to contribute substantially to sustainable heat production. To realize this potential, the availability of competitive, sustainable and cost effective optical coatings for solar collectors is a prerequisite. The coatings used today are primarily produced with expensive vacuum-based deposition techniques, transferring a hampering cost to the collectors, which impede the deployment of solar thermal as an energy source. Herein, we show that by leveraging scalable deposition techniques, with elaborate material choices and innovative nanoscale designs, it is possible to produce sustainable coatings that are highly competitive with regards to cost and performance.Using a scalable aerosol-based deposition technique, an antireflective mesoporous silica coating, commonly implemented in advanced solar technologies, is produced with an ordered hexagonal pore structure. The attention to optical thickness and pore structure facilitates a superior performance and an increased durability, making it especially suitable for arid climates. Moreover, we present several methods to achieve solar selectivity for the receiver. We leverage the large potential window of a deep eutectic solvent to facilitate electrodeposition of a texture-based cobalt-chromium coating, making an otherwise unsustainable technique viable today. High selectivity is also achieved by manipulating interference effects in coatings produced through precise control of thermal annealing of steel and ultrasonic spray coating of carbon nanotube composites. Such optical effects are only achieved for selective coatings deposited with more advanced and expensive techniques.Science is an iterative process of small incremental advances, often seemingly insignificant in the moment, which over time accumulate to surprisingly quick change. Here we present examples of sustainable, scalable, durable and cost competitive antireflective and solar selective coatings, thereby hopefully contributing to an accelerated implementation of solar thermal technologies.

Place, publisher, year, edition, pages
Umeå: Umeå University, 2025. p. 64
Keywords
Solar thermal collectors, optical coatings, solar selective coatings, antireflective coatings
National Category
Nanotechnology for Energy Applications
Research subject
Physics; Materials Science; nanomaterials
Identifiers
urn:nbn:se:umu:diva-238174 (URN)978-91-8070-654-4 (ISBN)978-91-8070-655-1 (ISBN)
Public defence
2025-05-23, KB301-Lilla hörsalen, Linnaeus väg 6, 907 36 Umeå, Umeå, 09:00 (English)
Opponent
Supervisors
Note

In thesis listed paper "Solar selective carbon nanotube composite coatings on optically tunable undercoating" is in the printed thesis published with title "Towards Solar Selective Carbon Nanotube Composites on Optically Tunable Undercoatings". 

Available from: 2025-04-30 Created: 2025-04-25 Last updated: 2025-04-28Bibliographically approved

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Zäll, ErikSegervald, JonasLundberg, PetterWågberg, Thomas

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