Short-chain ligand achieves ultra-stable CsPbX3 perovskite quantum dots for white light-emitting diodesShow others and affiliations
2024 (English)In: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 124, no 4, article id 041106Article in journal (Refereed) Published
Abstract [en]
All-inorganic perovskite quantum dots (PeQDs) have aroused great research interest in white light-emitting diodes (WLED) due to their excellent optoelectronic properties, but the poor stability, caused by dynamically binding long-chain capping ligands, hinders their future practical applications. To address this issue, here, we exploit short-chain butyric acid (BA) to replace long-chain oleic acid (OA) as capping ligand of CsPbX3 PeQDs by a hot-injection method. The addition of BA not only makes the morphology of CsPbBr3 PeQDs uniform and improves the crystallinity but also effectively suppresses nonradiative recombination, achieving a near unit photoluminescence quantum yield of 96%. The BA capped CsPbBr3 PeQDs exhibit high stability up to 180 d stored in ambient environment and also significantly improved resistance against polar solvent, ultra-violet lamp irradiation, and heat, which is rationalized by the strong binding capacity and shortened distance of BA to the PeQDs through ab initio calculations. Furthermore, by combining green-emission CsPbBr3 and red-emission CsPbBr0.8I2.2 PeQDs with blue GaN chip, we achieved WLEDs with excellent luminous properties, showing their great potential in practical application of wide-color-gamut display and lighting.
Place, publisher, year, edition, pages
American Institute of Physics (AIP), 2024. Vol. 124, no 4, article id 041106
National Category
Materials Engineering Materials Chemistry
Research subject
Materials Science
Identifiers
URN: urn:nbn:se:umu:diva-220079DOI: 10.1063/5.0176754ISI: 001149415000002Scopus ID: 2-s2.0-85183316634OAI: oai:DiVA.org:umu-220079DiVA, id: diva2:1831958
Funder
Bertil & Britt Svenssons Stiftelse för Belysningsteknik, No. 2019-85532024-01-272024-01-272024-05-27Bibliographically approved