Umeå University's logo

umu.sePublications
System disruptions
There are recurring service disruptions on some of the search portals due to high traffic. We are working to resolve the issue, you may temporarily encounter an error message.
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Thermal conductivity of normal and deuterated tetrahydrofuran clathrate hydrates
Umeå University, Faculty of Science and Technology, Department of Physics.
Umeå University, Faculty of Science and Technology, Department of Physics.
1996 (English)In: Journal of Physics and Chemistry of Solids, ISSN 0022-3697, E-ISSN 1879-2553, Vol. 57, no 1, p. 125-132Article in journal (Refereed) Published
Abstract [en]

The thermal conductivity λ of normal and deuterated tetrahydrofuran (THF) clathrate hydrates has been measured at temperatures in the range 55-250 K and at pressures up to 0.16 GPa. The normal and deuterated samples exhibited the same values of λ to within 5%. At isobaric heating, the transition from the proton ordered low temperature (LT) phase to the proton disordered high temperature (HT) phase was detected as a discontinuous decrease of λ by about 15% for both the normal and the deuterated samples. The magnitude is nearly the same as that found previously for the related transition phase XI → phase Ih of ice and might be due to a change in the lattice anharmonicity. The thermal conductivity of the LT and HT phases increased slightly with increasing temperature and, hence, these crystalline phases exhibited both a glass-like λ(T). These results can be described using the resonance scattering model in which the phonons are scattered against THF vibrations. The LT phase of both samples exhibited a slight increase of λ with increasing pressure whereas that of the HT phases was roughly independent of pressure, showing that λ does not depend on density.

Place, publisher, year, edition, pages
Elsevier, 1996. Vol. 57, no 1, p. 125-132
Keywords [en]
Thermal conductivity, tetrahydrofuran, clathrate hydrate
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:umu:diva-223701DOI: 10.1016/0022-3697(95)00157-3ISI: A1996TN22000016Scopus ID: 2-s2.0-0000134986OAI: oai:DiVA.org:umu-223701DiVA, id: diva2:1854024
Available from: 2024-04-24 Created: 2024-04-24 Last updated: 2024-04-24Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus
By organisation
Department of Physics
In the same journal
Journal of Physics and Chemistry of Solids
Condensed Matter Physics

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 68 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf