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Towards solar selective carbon nanotube composites on optically tunable undercoatings
Umeå University, Faculty of Science and Technology, Department of Physics. (Nano for Energy)
Umeå University, Faculty of Science and Technology, Department of Physics. (Nano for Energy)ORCID iD: 0009-0002-9248-5748
Umeå University, Faculty of Science and Technology, Department of Physics. (Organic Photonics and Electronics)ORCID iD: 0000-0003-1256-149x
Linköping University, Linköping, Sweden. (Thin Film Physics Division)
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(English)Manuscript (preprint) (Other academic)
Abstract [en]

Realizing the huge potential of solar thermal collectors depends on the reduction in levelized cost of energy, intimately related to production techniques, supply chains, industrial incorporation, and component cost. A key component in solar thermal collectors is the receiver with its solar selective coating, leveraging a high solar weighted absorptance, αS, and low thermal emittance, εT, to maximize the solar-to-thermal conversion efficiency. Herein, a solar selective multi-walled carbon nanotube (MWCNT) silica composite is deposited on a thermally induced oxide undercoating using highly scalable, cheap and sustainable methods and materials. The undercoating is optically tuned through manipulation of destructive interference to reduce reflectance in the visible wavelength region, to compliment the absorptance of the CNT composite dominated by π-plasmon excitation centered in the UV-region. Optimization of the CNT composite composition and layer stack configuration is achieved by the successful development of models to simulate the optical properties of both the oxide undercoating and the MWCNT silica composite top-coating. The tools and methods developed here take us closer to achieving sustainable and cost competitive coatings needed to realize the potential of solar thermal.

Keywords [en]
Solar energy, Carbon nanotubes, CNT composite, Solar selective coating, Solar absorber, Optical simulations, Optical coatings
National Category
Nanotechnology for Energy Applications
Identifiers
URN: urn:nbn:se:umu:diva-238173OAI: oai:DiVA.org:umu-238173DiVA, id: diva2:1954549
Funder
EU, Horizon 2020, 884213Swedish Research Council, 2021-04629Swedish Energy Agency, 45419-1EU, European Research Council, 101096650Knut and Alice Wallenberg Foundation, WISE-IP01-D01Available from: 2025-04-25 Created: 2025-04-25 Last updated: 2025-04-25Bibliographically approved
In thesis
1. Heating a sustainable future: optical coatings for solar collectors
Open this publication in new window or tab >>Heating a sustainable future: optical coatings for solar collectors
2025 (English)Doctoral thesis, comprehensive summary (Other academic)
Alternative title[sv]
Uppvärmning av en hållbar framtid : optiska beläggningar för solfångare
Abstract [en]

The green transition is the great undertaking of our time, and it will require significant ingenuity and change in all areas of society. Most urgently, perhaps, regarding energy, where the demand for transport, electricity and heat must be met by renewables instead of fossil fuels. Solar thermal is one alternative with the potential to contribute substantially to sustainable heat production. To realize this potential, the availability of competitive, sustainable and cost effective optical coatings for solar collectors is a prerequisite. The coatings used today are primarily produced with expensive vacuum-based deposition techniques, transferring a hampering cost to the collectors, which impede the deployment of solar thermal as an energy source. Herein, we show that by leveraging scalable deposition techniques, with elaborate material choices and innovative nanoscale designs, it is possible to produce sustainable coatings that are highly competitive with regards to cost and performance.Using a scalable aerosol-based deposition technique, an antireflective mesoporous silica coating, commonly implemented in advanced solar technologies, is produced with an ordered hexagonal pore structure. The attention to optical thickness and pore structure facilitates a superior performance and an increased durability, making it especially suitable for arid climates. Moreover, we present several methods to achieve solar selectivity for the receiver. We leverage the large potential window of a deep eutectic solvent to facilitate electrodeposition of a texture-based cobalt-chromium coating, making an otherwise unsustainable technique viable today. High selectivity is also achieved by manipulating interference effects in coatings produced through precise control of thermal annealing of steel and ultrasonic spray coating of carbon nanotube composites. Such optical effects are only achieved for selective coatings deposited with more advanced and expensive techniques.Science is an iterative process of small incremental advances, often seemingly insignificant in the moment, which over time accumulate to surprisingly quick change. Here we present examples of sustainable, scalable, durable and cost competitive antireflective and solar selective coatings, thereby hopefully contributing to an accelerated implementation of solar thermal technologies.

Place, publisher, year, edition, pages
Umeå: Umeå University, 2025. p. 64
Keywords
Solar thermal collectors, optical coatings, solar selective coatings, antireflective coatings
National Category
Nanotechnology for Energy Applications
Research subject
Physics; Materials Science; nanomaterials
Identifiers
urn:nbn:se:umu:diva-238174 (URN)978-91-8070-654-4 (ISBN)978-91-8070-655-1 (ISBN)
Public defence
2025-05-23, KB301-Lilla hörsalen, Linnaeus väg 6, 907 36 Umeå, Umeå, 09:00 (English)
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Supervisors
Note

In thesis listed paper "Solar selective carbon nanotube composite coatings on optically tunable undercoating" is in the printed thesis published with title "Towards Solar Selective Carbon Nanotube Composites on Optically Tunable Undercoatings". 

Available from: 2025-04-30 Created: 2025-04-25 Last updated: 2025-04-28Bibliographically approved

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Zäll, ErikSegervald, JonasRàfols-Ribé, JoanLarsen, ChristianGracia-Espino, EduardoEdman, LudvigWågberg, Thomas

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