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Access to pyrazolo[1,5-a]pyrimidinone regioisomers from acylated meldrum’s acids
Umeå University, Faculty of Science and Technology, Department of Chemistry.
Umeå University, Faculty of Science and Technology, Department of Chemistry.ORCID iD: 0000-0003-2523-1940
2026 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 28, no 1, p. 157-162Article in journal (Refereed) Published
Abstract [en]

Two complementary and efficient methods for the regioselective synthesis of functionalized pyrazolo[1,5-a]pyrimidinones were developed from 3-aminopyrazoles and acylated Meldrum’s acids. Fine-tuning the reaction conditions enables selective access to either pyrazolo[1,5-a]pyrimidin-5-ones or -7-ones in high yields. This protocol offers a reliable route to pyrazolo[1,5-a]pyrimidin-5-ones, a subclass with few reported syntheses, and highlights the value of acylated Meldrum’s acids as building blocks for regioselective heterocycle synthesis and biologically relevant scaffold generation.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2026. Vol. 28, no 1, p. 157-162
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:umu:diva-248973DOI: 10.1021/acs.orglett.5c04435ISI: 001644825800001PubMedID: 41427767Scopus ID: 2-s2.0-105027139726OAI: oai:DiVA.org:umu-248973DiVA, id: diva2:2035669
Funder
Cancerforskningsfonden i Norrland, AMP 24-1154Lions Cancerforskningsfond i Norr, LP 24-2352Available from: 2026-02-05 Created: 2026-02-05 Last updated: 2026-02-05Bibliographically approved

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Donzel, MaximeChorell, Erik

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